Preliminary identification of woods from Mexican pines by ATR-FTIR spectroscopy
DOI:
https://doi.org/10.29298/rmcf.v13i72.1186Keywords:
ATR-FTIR Spectroscopy, Spectral library, Wood, Wood chemistry, Mexican pines, XylothequeAbstract
A wide variety of species of the genus Pinus are widely distributed in Mexico, and are of great commercial importance, so proper identification of its wood is important. This is not an easy task, due to the anatomical and chemical characteristics of the pines; for this reason, the potential of an ATR-FTIR spectral reference library of wood (spectral library) was investigated. The spectra of woods have enough differences to implement an identification process by spectral comparison. Spectral library was created using samples from xylotheque in the Department of Wood, Cellulose and Paper (Universidad de Guadalajara), which have been rigorously identified. The spectra of nine pine species (Pinus arizonica, P. ayacahuite, P. devoniana, P. douglasiana, P. durangensis, P. oocarpa, P. patula, P. pringlei, and P. pseudostrobus), were obtained from three different places, so that spectral library has 27 spectra. To determine the viability of method, other samples from xylotheque were analyzed, different from those of spectral library, of five species (P. ayacahuite, P. devoniana, P. oocarpa, P. pseudostrobus, and Cupressus arizonica), obtaining in three cases the highest correlations for correct species, and a second place for the other two. The use of a spectral library is a quick method, which can help in identification of wood and establish its origin. The technique could be improved by developing a spectral and statistical treatment that considers the particularities of lignocellulosic materials.
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References
Gasson, P. 2011. How precise can wood identification be? Wood anatomy’s role in support of the legal timber trade, especially cites. IAWA Journal 32(2):137–154. Doi: 10.1163/22941932-90000049. DOI: https://doi.org/10.1163/22941932-90000049
Grebner, D. L., P. Bettinger and J. P. Siry. 2014. Introduction to Forestry and Natural Resources. Academic Press. San Diego, CA, USA. 508 p. DOI: https://doi.org/10.1016/B978-0-12-386901-2.00016-6
Instituto Nacional de Estadística y Geografía (Inegi). 2021. Anuario estadístico y geográfico de los Estados Unidos Mexicanos 2020. Versión actuaslizada. Instituto Nacional de Estadística y Geografía. Aguascalientes, Ags. México. 856 p.
Keeley, J. E. 2012. Ecology and evolution of pine life histories. Annals of Forest Science 69(4):445–453. Doi: 10.1007/s13595-012-0201-8. DOI: https://doi.org/10.1007/s13595-012-0201-8
Menges, F. 2020. Spectragryph-optical spectroscopy software- (version 1.2.15). Spectroscopy Ninja. Oberstdorf, Germany. https://www.effemm2.de/spectragryph/index.html. (30 de abril de 2021).
Ochiai, S. 2015. Attenuated Total Reflection Measurements. In: Tasumi, M. (ed.). Introduction to experimental infrared spectroscopy : fundamentals and practical methods. John Wiley & Sons, Ltd. Chichester, W. Susx., UK. pp. 179-198.
Özgenç, O., S. Durmaz, I. H. Boyaci and H. Eksi-Kocak. 2017. Determination of chemical changes in heat-treated wood using ATR-FTIR and FT Raman spectrometry. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 171:395-400. Doi: 10.1016/j.saa.2016.08.026. DOI: https://doi.org/10.1016/j.saa.2016.08.026
PerkinElmer, Inc. 2013. Spectrum (version 10.4.00.0190). PerkinElmer For the better. USA. https://www.perkinelmer.com/es/product/software-kit-spectrum-10-lx108873. (30 de abril de 2021).
PerkinElmer, Inc. 2014. AssureID Method Explorer (version 4.3.8.210). PerkinElmer For the better. Spain. https://www.perkinelmer.com/es/product/s-w-assureid-std-full-lx108889. (30 de abril de 2021).
Rowell, R. M., R. Pettersen and M. A. Tshabalala. 2013. Cell wall chemistry. In: Rowell, R. M. (ed.) Handbook of wood chemistry and wood composites. CRC Press. Boca Raton, FL, USA. pp. 33-72. DOI: https://doi.org/10.1201/b12487-5
Savistky, A. y M. J. E. Golay. 1964. Smoothing and Differentiation of Data by Simplified Least Squares Procedures. Analytical Chemmistry 36(8):1627–1639. Doi: 10.1021/ac60214a047. DOI: https://doi.org/10.1021/ac60214a047
Sekhar T., A. C., M. A. Garcia M., Z. Movasaghi, S. Rehman and I. U. Rehman. 2017. Advances in Fourier transform infrared (FTIR) spectroscopy of biological tissues. Applied Spectroscopy Reviews 52(5):456–506. Doi: 10.1080/05704928.2016.1230863. DOI: https://doi.org/10.1080/05704928.2016.1230863
Sharma, V., J. Yadav, R. Kumar, D. Tesarova, A. Ekielski and P. Kumar M. 2020. On the rapid and non-destructive approach for wood identification using ATR-FTIR spectroscopy and chemometric methods. Vibrational Spectroscopy 110:103097. Doi: 10.1016/j.vibspec.2020.103097. DOI: https://doi.org/10.1016/j.vibspec.2020.103097
Singh, R. 2016. Chemotaxonomy: a tool for plant classification. Journal of Medicinal Plants Studies 4(2):90–93. https://www.plantsjournal.com/archives/2016/vol4issue3/PartB/4-2-17.pdf (30 de abril de 2021).
Tasumi, M. 2015. Introduction to infrared spectroscopy. In: Tasumi, M. (ed.). Introduction to experimental infrared spectroscopy : fundamentals and practical methods. John Wiley & Sons, Ltd. Chichester, W. Susx., UK. pp. 3-13.
Traoré, M., J. Kaal and A. Martínez C. 2018. Differentiation between pine woods according to species and growing location using FTIR-ATR. Wood Science and Technology 52(2):487–504. Doi: 10.1007/s00226-017-0967-9. DOI: https://doi.org/10.1007/s00226-017-0967-9
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